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101.
102.
Yong Li Juan Wang HuiXing Huang Jia Wang Mi Zhang MMeng Liang 《Advanced Powder Technology》2019,30(8):1442-1449
The electronic conductivity enhanced has been extensively studied and reported in lithium iron phosph-ate (LiFePO4). However, only few existing literatures are available for researchers to enhance simultaneously the ion and electronic conductivity of LiFePO4. Herein, we disclose that the LiFePO4 is co-coated with novel GdPO4 and Carbon via a hydrothermal-assisted solid-phase method, contributing to particle size and dispersibility. What surprising is that the ionic and electronic conductivity of the material is significantly enhanced, and the interfacial side reaction is effectively inhibited between the materials and the electrolytes. The diverse proportions of the mixed coating (LiFePO4/C&xGdPO4 (x = 0, 1 wt%, 2 wt%, 3 wt%, 4 wt%)) are synthesized compared with bare LiFePO4. The experimental results suggest that LiFePO4/C&0.03GdPO4 exhibits the most excellent electrochemical performance. There is discharge capacity of 158, 148.8, 141.6, 134.9, 121.8, 104.9, and 86.7mAh/g at 0.1, 0.2, 0.5, 1, 2, 5, and 10 C rates, respectively. 相似文献
103.
Yifan Zhang Shaowei Bo Tao Feng Xialing Qin Yilin Wan Shanshan Jiang Chunxiao Li Jing Lin Tianfu Wang Xin Zhou Zhong‐Xing Jiang Peng Huang 《Advanced materials (Deerfield Beach, Fla.)》2019,31(21)
To design a clinically translatable nanomedicine for photodynamic theranostics, the ingredients should be carefully considered. A high content of nanocarriers may cause extra toxicity in metabolism, and multiple theranostic agents would complicate the preparation process. These issues would be of less concern if the nanocarrier itself has most of the theranostic functions. In this work, a poly(ethylene glycol)‐boron dipyrromethene amphiphile (PEG‐F54‐BODIPY) with 54 fluorine‐19 (19F) is synthesized and employed to emulsify perfluorohexane (PFH) into a theranostic nanoemulsion (PFH@PEG‐F54‐BODIPY). The as‐prepared PFH@PEG‐F54‐BODIPY can perform architecture‐dependent fluorescence/photoacoustic/19F magnetic resonance multimodal imaging, providing more information about the in vivo structure evolution of nanomedicine. Importantly, this nanoemulsion significantly enhances the therapeutic effect of BODIPY through both the high oxygen dissolving capability and less self‐quenching of BODIPY molecules. More interestingly, PFH@PEG‐F54‐BODIPY shows high level of tumor accumulation and long tumor retention time, allowing a repeated light irradiation after a single‐dose intravenous injection. The “all‐in‐one” photodynamic theranostic nanoemulsion has simple composition, remarkable theranostic efficacy, and novel treatment pattern, and thus presents an intriguing avenue to developing clinically translatable theranostic agents. 相似文献
104.
Existing standards show a clear discrepancy in the specification of the maximum proton energy for qualified ground-based evaluation of single-event effects,which can range from 180 to 500 MeV. This work finds that the threshold linear energy transfer of a tested device is a critical parameter for determining the maximum proton energy. The inner mechanisms are further revealed. Highenergy deposition events(10 MeV) in sensitive volumes are attributed to the interaction between protons and the tungsten vias in the metallization layers. 相似文献
105.
In this paper, we focus on the pinning exponential synchronisation and passivity of coupled reaction–diffusion neural networks (CRDNNs) with and without parametric uncertainties, respectively. On the one hand, with the help of designed nonlinear pinning controllers and Lyapunov functional method, sufficient conditions are established to let the CRDNNs with hybrid coupling and mixed time-varying delays realise exponential synchronisation and passivity. On the other hand, considering that the external perturbations may lead the reaction–diffusion neural networks (RDNNs) parameters to containing uncertainties, the robust pinning exponential synchronisation and robust pinning passivity for coupled delayed RDNNs with parametric uncertainties are investigated by designing appropriate pinning control strategies. Finally, the effectiveness of the theoretical results are substantiated by the two given numerical examples. 相似文献
106.
Liu Chunwei Huang Shuigen Blanpain Bart Guo Muxing 《Metallurgical and Materials Transactions B》2019,50(1):271-281
Metallurgical and Materials Transactions B - Basic oxygen furnace (BOF) steel slag is a main byproduct that is produced during the converter steelmaking process. The volume instability and fast... 相似文献
107.
Lihong Zhang Xiangyu Guo Shiping Huang 《International Journal of Hydrogen Energy》2021,46(53):26950-26960
By virtue of their wide band gaps, the photocatalytic ability of MnPS3 and ZnPS3 for water splitting is subject to narrow visible light adsorption. In this work, the first-principle calculations are adopted to study the impact of biaxial strain and electric field on photocatalytic performance of MnPS3 and ZnPS3. Our theoretical calculations demonstrate that MnPS3 under ?10% biaxial strain, ?5% biaxial strain and a 0.05 V/Å electric field possess appropriate band gaps and band edge positions required for photocatalytic water splitting as well as pronounced absorbance in the visible and ultraviolet spectrum. Whereas, the band structures for ZnPS3 can not be altered significantly either by applying biaxial strain or electric field. Through the free energy change analysis, it is found that water splitting reactions on MnPS3 under ?10% biaxial strain as well as ?5% biaxial strain can be thermodynamically spontaneous at pH 7–10 using natural sunlight. 相似文献
108.
109.
当下建筑业的能源高消耗占据生态能源浪费的较大比例,在此背景下,既有建筑绿色改造成为当下生态环境可持续发展必不可少的课题之一.从建筑业大视角上进行阐述,首先概述了既有建筑绿色改造提出的背景、含义及重要性,其次分析既有建筑在绿色改造工程推进过程中遇到的挑战,最后结合国内外相关绿色改造成熟做法针对上述问题提出了5个建议. 相似文献
110.